Alpha Crypter v.1.0 this is a software that helps encrypting files using a simple self-created encryption.Send your encrypted files by email, simply by encrypting and attaching.This small application uses the highly regarded Blowfish algorithm. Encrypt and decrypt your files with 448bit security (considered military grade).Crypter - 448bit encryption with Blowfish v.1.2.It's very useful to prevent web pages scanning by the crawlers gathering e-mail addresses for broadcasting spam messages on next step. URI Crypter v.3.1 This program allows you to substitute URI for symbol codes of ASCII table.File encryption and decryption is available since version. It provides textboxes to enter plaintext or ciphers. GPG-Crypter v.0.3.5 GPG- Crypter is a GTK+ frontend to GPG and it is intended to de- and encrypt text into ASCII-armored gpg-ciphers.A version of File Crypter is included as an example in the xCrypter Library and is called "ncrypter" which is short for "new. File Crypter v.1.5 File Crypter is a Simple program, that is able to encrypt your files and decrypt them.It uses a modern modification of the DES algorithm for encryption - one of the best cryptographic. Easy Crypter 2012 v.3.5 Easy Crypter 2012 - a safe and convenient program which allows you to encrypt/decrypt single or multiple files as well as text, such as e-mail.Aloaha PDF Crypter v.3.9.115 Aloaha PDF Crypter 3.9.115 is an application for prevent re-distribution of confidential documents or sell documents/ebooks.Data are encrypted with SecureDNA, so, who hasn't got the password can't. In virtual hard disks you can install programs, copy files, do everything you want. Bildsoft Crypter v.2006 Bildsoft Crypter: the user has the possibility to create, hide and protect virtual hard disk.Easy Crypter 2010 is easy to use and does not require any knowledge in the cryptography sphere. Easy Crypter 2010 v.3.21 Easy Crypter 2010 - a safe and convenient program which allows you to encrypt/ decrypt single or multiple files as well as text, such as e-mail. Mini Crypter v.2.1.9.8 Mini Crypter provides maximum protection against reverse engineering and antivirus detections, being the perfect choice for developers who want to add tough-to-crack protection to their software programs.This is our migration path for all the legacy Truecrypt Windows based installations. If you don't have to worry about IRL Adversaries / Quantum Computer Decryption, IMO this will more than serve your crypto needs. Love to see ARM support and a few more features if the foundation can see to expanding the product. Out of the box, the app natively supports AES-TwoFish-Serpent and combinations thereof, and subjectively speaking, it appears to be quite fast even with a 2 or 3 algorithm cascade on dinky 2 core and 4 core processors, but does take a bit of time to encrypt larger HDDs, especially when theres less processing horsepower / memory available.ĭefinitely no complaints for what's bundled in and the bootloader options are indeed versatile, and especially for what you have to pay (as in free :D). the big plus is that it is mature, it is still around after Truecrypt ended its development lifecycle.Ī quick review of the source indicates that it is quite well written although I have to say that we are not that well qualified to properly assess / be authoritative about optimizing cryptographic algorithms for x86 & 圆4 cores. The documentation is weak at the wiki-website level but hey, its a free product. It supports single platform (Windows only) and has no portable version.
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Leap can allow you to get into squares for crowd pushes, or next to the ball carrier, for blitzes that would be hard to dodge into. It will also allow you to set up more crowd pushes in your turn if they get blocked by the opposition. Side Step comes next as then you don’t have to be as wary of getting pushed into the crowd yourself and makes you a hassle next to ball carriers and receivers. I would suggest you build at least one with Block though and perhaps both, though you then need to look at Wrestle for your Linemen instead. Block is obviously good for when you are hitting players, especially if playing against Stunty players and if you have Juggernaut, Wrestle heavy teams. Assuming they don’t then your first choice will be whether you go for Block or Wrestle. Most Witch Elves will get similar builds depending on when or if they roll a stat increase or a double skill roll. Normal: Block, Side Step, Leap/Tackle/Pro/Diving Tackle.You also have to consider other teams fouling them as well, with low armour it doesn’t take many assists to guarantee an injury roll, so be careful about getting them isolated. Especially be aware of leaving them on the sideline (or near it) if you don’t yet have Side Step as well. Frenzy can also sometimes be a problem if you don’t get a knock down on the first block, so always check what the second block will be before you go ahead and do the first one. Their first skill most of the time will be either Block or Wrestle (I’ll go into that below) as you need the protection and it increases their hitting ability. The main drawbacks to a Witch Elf though are the cost to hire them and their low armour. It is also obviously handy if you can do the same thing to the opposing ball carrier. This is especially effective near the side lines and you can engineer crowd pushes from further infield than is expected. Another nice trick is to use pushbacks to push opposing players next to a prone Witch Elf and then use Jump Up to hit them again. You can effectively get an extra blitz, using the main blitz action elsewhere and the Jump Up block to hit another player that would have otherwise used a blitz action. It increases their blitzing range which the other coach may forget. Not to mention the ability to block from prone can also lead to extra advantages. The other main benefit a Witch Elf starts with is the Jump Up skill, if they move into range as a receiver, then it is no good just knocking them over, you need to break armour to eliminate them as a threat. I’ve been able to do this against quite a few coaches who thought their players safe from Frenzy, Leap makes this even easier. A Witch Elf has enough movement and agility to be able to get around to crowd push a player that is staggered behind a team mate thinking they are safe from the crowd push. Also the way some teams will set up their players near the sideline against Frenzy players. If you are used to playing against the Big Guys with Frenzy and see how easy it is to manipulate their movement and bog them down, or see the range they can move, a Witch Elf can throw up some surprise blitzes that take your players into the crowd. Against any side who has Frenzy teams have to be careful near the side line, though when that player can dodge with ease and also move far enough to get to you, then you have to be even more vigilant. In the hands of a good coach though you can really open up their potential.Ī Witch Elf has two main threats that opposing teams really look out for, the main one is Frenzy coupled with their high movement and mobility. For inexperienced players they can be tricky to use initially, with Frenzy and a lack of Block. They will draw attention though and get targeted for blitzes and fouls. Witch Elves are a great asset to the Dark Elf team and are players that other teams are usually very wary of. The first step to achieving this is by creating a function, and calling the function in the onclick attribute, for example: Especially on larger applications, more maintainable code is achieved by separating HTML markup from JavaScript interaction logic. Whilst it is possible to write JavaScript directly inside the HTML event attributes (such as onclick="this.className =' M圜lass'") this is not recommended behaviour. # Assigning these actions to onclick events: The same regex used above for removing a class can also be used as a check as to whether a particular class exists: if ( document.getElementById("MyElement").className.match(/(?:^|\s)M圜lass(?!\S)/) ) To check if a class is already applied to an element: The g flag tells the replace to repeat as required, in case the class name has been added multiple times. # Ensures there is no non-space character following (?!\S) # Negative lookahead to verify the above is the whole classname M圜lass # The literal text for the classname to remove * Code wrapped for readability - above is all one statement */Īn explanation of this regex is as follows: (?:^|\s) # Match the start of the string or any single whitespace character To remove a single class to an element, without affecting other potential classes, a simple regex replace is required: document.getElementById("MyElement").className =ĭocument.getElementById("MyElement").className.replace To add a class to an element, without removing/affecting existing values, append a space and the new classname, like so: document.getElementById("MyElement").className = " M圜lass" (You can use a space-delimited list to apply multiple classes.) To add an additional class to an element: To replace all existing classes with one or more new classes, set the className attribute: document.getElementById("MyElement").className = "M圜lass" The standard JavaScript way to select an element is using document.getElementById("Id"), which is what the following examples use - you can of course obtain elements in other ways, and in the right situation may simply use this instead - however, going into detail on this is beyond the scope of the answer. It is, though, getting more and more supported. Unfortunately, these do not work in Internet Explorer prior to v10, though there is a shim to add support for it to IE8 and IE9, available from this page. If ( document.getElementById("MyElement").ntains('M圜lass') )ĭocument.getElementById("MyElement").classList.toggle('M圜lass') Modern browsers have added classList which provides methods to make it easier to manipulate classes without needing a library: document.getElementById("MyElement").classList.add('M圜lass') ĭocument.getElementById("MyElement").classList.remove('M圜lass') Modern HTML5 Techniques for changing classes Martial professions may be interested in completing Factions earlier because of the skill "Save Yourselves!". In addition, the sunspear PvE skills, which include Critical Agility, Seed of Life, Cry of Pain, Necrosis, Whirlwind Attack and Vampirism, are very good. This includes heroes such as Acolyte Sousuke/ Acolyte Jin and Olias. Perks: unlock locations required for War in Kryta and Hearts of the NorthĪlternatively, travel to Elona before going any further in Eye of the North storyline, as most of the heroes can be acquired early during the Nightfall storyline. Perks: Short, a few more PvE skills, unlocks locations required for Winds of Change Perks: Short, good heroes, good PvE skills, opens up your Hall of Monuments via the four Monumental Tapestries
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It works over local networks, over the internet, over 3G/4G, and so on. The two are connected and the other device’s video stream is displayed. To set it up, you point the camera at the QR code on the other device. This app is also available for Android phones and tablets, the iPhone and iPad, Windows PC and Apple Mac.ĪtHome Camera is used to view the output from AtHome Video streamer. When you are ready, there is a button to display a QR code on the screen. Start the app and it shows a live picture from the device’s camera. You might need to prop it up on a stand of some sort to it is facing into the room. The PC, Mac, phone or tablet must be switched on, although the screen does not have to be on. ( AtHome Video Streamer runs on the device with the camera and it must be positioned so that it is facing whatever it is you want to watch, your baby’s cot, dog’s bed, hamster cage, and so on. This app is available for Android phones and tablets, the iPhone and iPad, Windows PC and Apple Mac. Two devices are involved and one has the camera and it streams the video, and the other receives the video and shows it on the screen. So how do you set up a remote camera and watch the video stream on your phone?. Related: 5 Android Wi-Fi analysers to detect intruders on your network Set up video surveillance These are just two possible scenarios where it is useful to be able to see what is happening in your home when you are busy elsewhere and there are many more. You can even speak to them! That might provide them with some comfort and calm them down if they look concerned. You can set up a camera to watch them while you are out or at work. is your dog going crazy and tearing up the home? Is it sleeping? What is your cat doing? Are your pets playing or fighting? Video surveillance can also be used to monitor your paranoid pets at home while you are at work. You can keep an eye on your youngsters while you get on with something else. It is possible to set up a video camera and stream the video to your phone wherever you are, such as in the lounge watching television or in the kitchen preparing a meal. Are they sleeping or awake? Are they crying or happy? Do they need your attention? Is there a problem? Sometimes you want to know what is happening in another room in your home, such as your baby’s room or a young child’s. See what’s happening, live on your phone no matter where you are. Set up a video surveillance system in your home for security and monitor it using your mobile phone from anywhere.
Your objective will be to Free the Villagers. Insect #5 is located near the end of the game. You will need to jump on one of your resistance friend’s heads to reach the breakable wall and kick it. There is a breakable wall to the left of the elevator in the Old Mine. Insect #4 is located near the entrance elevator of the Old Mine. Continue to the right and water the next plant to jump up (don’t fall down the hole to the dungeon) to the surface and find the insect under the logs. In the next area, use the hook to flood the area and place an acorn on the button to get to the next area. You will need to water a plant with your hat to make it up to the next area. After getting the watering can hat through story progression, head to the right from the resistance base to find a jagged wall to enter. Insect #3 is located under some logs in the Forest. Kick the rock to the left and use the mushroom to jump to the left through the jagged wall. From the bottom of this area, there is a mushroom and rock that you can move around. You will be climbing a blue structure with mushrooms to jump on. Insect #2 is located in the transitional area between the Village and Forest. Use the mushroom to jump up to the platform and find the insect. As you head down hill, you will see a jagged wall that you can enter. Insect #1 is located at the beginning of the game after exiting your cave. Insect #5 needs to be collected before completing the story or you will need to start a new playthrough and collect them all again. There are 5 in total and all of them (except #5) can be collected during or after completing the adventure mode story. MISSABLE: Insects are one of the types of collectibles in the game. See the video below for all of the locations. The rest are in the single player adventure story mode however, trophy #11 and #12 must be collected before completing the story or you will need to start a new playthrough and collect all of them again. There are 18 in total 5 of them are only available in coop. MISSABLE: Trophies are one of the types of collectibles in the game. You can spend these coins in shops without negatively impacting your progress toward this achievement as it is cumulative. You can continue collecting them after finishing the story, if you still haven't collected 70. Just play through the game as normal and collect as many coins as you can along the way. These coins are located in every area and in the transitional areas. Sunshine will be introduced and throw coins all over the game world. Toward the end of the Village portion of the story, Mr. Plus, another quick completion who could complain? Edited Jby UntilTammaroYT While it doesn’t pose any immense challenges or redefine the genre, it is a quick and enjoyable experience suitable for any type of gamer. Pikuniku is a fun, cute, and strange adventure from the purveyors of fun, cute, and strange games. Restart your game and grab anything you missed to get your 1000:1gs. You shouldn’t have anything to mop up unless you missed any of those missable achievements. Once you’ve had your fill of single player, hop over to the coop to pick up the coop specific achievements (“ You’re not helping” & “ Gotta go fast”). Pay special attention to the collectibles along the way and make sure to not miss any of the missable achievements (“ Suprematism”, “ Dancing machine”, " Right under your feet”, & “ Collector”) or you’ll need to start another whole playthrough. The couch coop has you play as either Piku or Niku in a number of challenging levels where the goal is to get the best completion time possible.įor the most part, you’ll just want to play the adventure story mode while following this guide to make sure you don’t miss anything. In adventure mode, you play as Piku, a feared “beast”, who turns out to not be that scary at all and help all the people who were once afraid of you. The world is strange, but playful with a straightforward story to tell. Pikuniku is a fun little platform adventure from Devolver Digital. Extra equipment needed: Two Controllers Does difficulty affect achievements: N/A Missable achievements: 4 (“ Suprematism”, “ Dancing machine”, " Right under your feet”, & “ Collector”) Minimum number of playthroughs needed: 1 Approximate amount of time to 1000:1gs:: 0-5 Hours Estimated achievement difficulty: 3/10 Settings and features we’ve added in recent packs will still be available in The Jackbox Party Pack 9. “What can I expect from The Jackbox Party Pack 9?” Because we have a speedy annual release cycle, the time between submission and release is super quick! As soon as we can, we pick a date and share it with the world! Until we pass the submission process, we’re unable to select a release date. It’s true that we usually release our new title around this time of year! In the time leading up to launch, we have to submit our game to all of the many platforms we’re available on. “Why did you make us wait so long to share a date?” In a totally unselfish attempt to ensure your hangouts are engaging and fun through the holiday season, we’ve decided that The Jackbox Party Pack 9 is coming to major digital platforms on Thursday, October 20th! We’re on cloud nine to have successfully finished what might be our best pack yet. Then, the Video Game Illuminati descended and told us that our selfishness would be punished with ten years of cursed parties if we didn’t see the error of our ways. It’s true that The Jackbox Party Pack 9 is so fun that we almost decided to keep it for ourselves. You don’t need extra controllers for extra players - everyone uses their phones or tablets to play! Games support up to 10 players and 10,000 audience members joining in the fun to impact the outcome of the game. Whether you’re hanging out with friends, having a remote happy hour, trying to make the holidays less awkward, or looking for your next game to stream, The Jackbox Party Pack 9 is here to spice things up. Based on the lowest unoccupied molecular orbital determination, the symmetry of the end orbitals is observed and the resulting product is estimated. The HOMO is the highest energy molecular. What is HOMO and LUMO ins spectroscopy HOMO is the highest occupied molecular orbital whereas LUMO is the lowest Unoccupied molecular orbital. Figure 9.26 Frontier molecular orbitals HOMO and LUMO. The lowest unoccupied molecular orbital is determined by the number of electrons filling the orbital and hence the symmetry is determined. HOMO stands for Highest occupied molecular orbital while LUMO stands for Least unoccupied molecular orbital. As their names imply, the HOMO is the molecular orbital that has the highest energy and contains electrons, while the LUMO is the lowest energy molecular orbital that does not contain electrons. Reactions, as the similar lobes has to overlap or detach. Lowest unoccupied molecular orbital has an important role in electrocyclic ring opening and closing explaining why DFT models could predict the electronic conductance in these. This conrotatory and disrotatory movement is dependent upon the condition employed either photochemical or thermal conditions. functional typically underestimate molecular HOMO-LUMO gaps by several eVs. The molecular structure and spectra explained by Gaussian hybrid. The orbitals at the ends of an open chain molecule or orbitals involved during bond breaking undergoes con–rotation (rotation of both orbitals in similar direction) or dis–rotation (rotation of both orbitals in opposite direction) based on the number of electrons involved in the molecule. HOMO-LUMO energy gap and other related molecular properties are also calculated. The formation of closed ring compounds or opening of ring compounds into open chain products are governed by some rules explained in frontier molecular orbital theory. Hence, smaller HOMO-LUMO gaps correspond to better stability.In Electrocyclic reactions, the reactions result in either open chain molecule formation or closed ring formation. If only one electron is present, it can occupy the BMO, also resulting in significant bonding, but since there is only one electron to contribute to the bonding, the bonding is not nearly as strong as in the case of two electron bonding. The greater the mobility of the #pi# electrons in large conjugated pi orbital systems, the greater the distribution of the energy throughout the molecule, stabilizing it. o Efficient overlap o Two paired electrons. When you have a large aromatic system in particular, small HOMO-LUMO gaps lead to mobile #\mathbf(pi)# electrons since it is easy for the electron to jump to a higher energy level that is close in energy. The larger the aromatic system is, the smaller the HOMO-LUMO gap! the Highest Occupied, HOMO and Lowest Unoccupied, LUMO). Interpreting Colors Electrophilic (HOMO) Frontier Surface, Blue, region most susceptible to attack by a electrophile Nucleophilic (LUMO) Frontier Surface. Hence, it is the most important energy gap to consider.Įxcitations becomes easier as the HOMO-LUMO gap converges, such as for large aromatic systems (like tetracene or benzopyrene), or for transition-metal complexes (that is why they tend to be colored). Woodward and Hoffmann showed that by examining the interaction of the frontier molecular orbitals (ie. HOMO and LUMO are acronyms for highest occupied molecular orbital and lowest unoccupied molecular orbital, respectively. That means they are closest in energy out of all orbitals in the molecule.ĭue to the energies of these orbitals being the closest of any orbitals of different energy levels, the HOMO-LUMO gap is where the most likely excitations can occur. Of the orbitals that have electrons, the HOMO is the highest in energy, and of the orbitals that don't, the LUMO is the lowest in energy. Sometimes the LUMO is UNUSUALLY low, like the one indicated in red on the far. Thus, of the two HOMO-LUMO interactions which are in general possible. Sometimes the HOMO is not only the highest in the molecule but is UNUSUALLY high, like the one indicated in red on the near right. The strength of the interaction is directly related to the HOMO-LUMO energy separation. explain the decrease in the HOMO-LUMO gap, or the red shift. Every molecule has a highest occupied molecular orbital (HOMO) and a lowest unoccupied molecular orbital (LUMO). Don't be confused though, because the LUMO is higher in energy than the HOMO. The absorbance edge (edge) is defined here as the wavelength at which A(base 10) ) 2 cm-1. HOMO stands for " Highest Occupied Molecular Orbital", and LUMO stands for " Lowest Unoccupied Molecular Orbital". |
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